An investigation into the structure and color stability of Polaroid 20×24 prints
DOI:
https://doi.org/10.23738/CCSJ.170107Keywords:
Instant Prints, Dye Diffusion, Polaroid 20×24, Polacolor, Microfading Testing, Light Stability, Polaroid ChocolateAbstract
Polaroid 20×24 prints, renowned for their distinctive large format and use by artists, have received limited attention within the conservation community. This study, conducted at the Art Institute of Chicago, examines the materials, structure, and stability of different generations of Polaroid 20×24 film, including Polacolor ER (P3), Polacolor Pro 100 (P6), Polacolor 7 (P7), and hybrid Chocolate prints. Utilizing a combination of non-invasive and invasive analytical techniques, such as SEM-EDS and FTIR, the research characterizes these materials and investigates light stability through microfading testing (MFT). Comparative MFT analyses of various dye colors across generations revealed specific vulnerabilities. These findings contribute valuable insights into the material composition of Polaroid 20x24 prints and inform display and preservation strategies, ensuring the longevity of these culturally significant artworks.
References
Adams, A. and Baker, R. (1978) Polaroid Land Photography. Boston: New York Graphic Society, pp. 58–59.
Asto, J. C. (2019) 20x24 Studio Berlin: Keeping Large Format Instant Photography Alive, The Phoblographer. Available at: https://www.thephoblographer.com/2019/02/10/20x24-studio-berlin-keeping-large-format-instant-photography-alive-today (Accessed: 11 October 2024).
Beltran, V.L., Pesme, C., Freeman, S.K. and Benson, M. (2021) Microfading Tester: Light Sensitivity Assessment and Role in Lighting Policy. Los Angeles: Getty Conservation Institute.
Bonanos, C. (2012) Instant: The Story of Polaroid. New York: Princeton Architectural Press, pp. 75–84.
Bushner, J. J. and Rantanen, W. J. (2024) Analysis of Three Photographic Paper Samples. SGS North America, Inc, pp. 1–8.
Casto, S. and Valverde, F. (2019) ‘Hinging and Float Mounting 20×24” Polaroid Prints and Negatives’, Topics in Photographic Preservation 18, pp. 1–3.
Eckert, R.D., Filosa, M.P., Gomes, G., Layne, A.R., Schwarz, M.C. and Taylor, L.D. (1998) ‘Photographic Element and Method’, U.S. Patent 5,756,253.
Fehervari, A.F., and Manning, J.J. (2002) ‘Image-Receiving Element’, U.S. Patent 6,403,278 B1.
Fujita, S. (2004) Organic Chemistry of Photography. Berlin, Heidelberg: Springer-Verlag, pp. 341–372.
Gomes, G., LaPointe, G.S. and Manning, J.J. (2005) ‘Image-Receiving Element’, U.S. Patent 6,946,232.
Gomes, G., (2024) Emails to Paulina Miąsik about Polaroid chemistry (September 2024-February 2025).
Holmquist, C. (2024) Email to Paulina Miąsik about Chocolate prints, (August 2024).
Image Permanence Institute (2010) Film Type Chart Dates, Graphics Atlas. Rochester, NY: Image Permanence Institute (IPI). Available at: http://www.graphicsatlas.org/media/images/id/Polaroid_Films.pdf (Accessed: 20 February 2025).
Kliem, P.O. and Mass, W. (1988) ‘Hybrid Color Films With Dye Developer and Thiazolidine Dye Releaser’. U.S. Patent 4,740,448.
Łojewski, T. and Grzelec, M. (2020) ‘Światłotrwałość i światłonietrwałość – o możliwościach wykorzystania wyników badań mikrofedometrycznych w ochronie zbiorów’, Notes Konserwatorski, 22_2020, p. 79, DOI:10.36155/NK.22.00003.
Mesquit, T. and Lemmen, B. (2005) ‘Coatings on Polaroid Prints’, in McCabe, C. (ed.) Coatings on Photographs: Materials, Techniques, and Conservation. Washington, D.C.: American Institute for Conservation, pp. 180–199.
Miąsik, P. and Pénichon, S. (2024) ‘Polaroid 20×24: Characterization and Investigation of Treatments and Preservation Methods’, Expect The Unexpected, 52nd Annual Meeting, May 20–24, Salt Lake City, Utah, American Institute for Conservation.
Michalski, S. (2017) Agent of Deterioration: Light, Ultraviolet and Infrared. Government of Canada. Available at: https://www.canada.ca/en/conservation-institute/services/agents-deterioration/light.html (Accessed: 11 Oct. 2024).
MSDS No. M-0579. Developer fluid contained in pod of film types 668, 668H, 108, 669, 661W, 669S, 108S, 669HS, 88, VIVA (COLOR), 661, 559, 559S, 58, 59, 808, 809, PCID ULTRAVIOLET; POLACOLOR ER; PRO-VIVID; Polaroid Corporation, Waltham, MA, July 7, 1998.
Panzer, M. (2008) ‘Big Artists, Big Camera: Not a Typical Polaroid’, The Wall Street Journal, Available at: https://www.wsj.com/articles/SB121797626872014909 (Accessed: 21 January 2025)
Pénichon, S. (2013) Twentieth-Century Color Photographs: Identification and Care. Los Angeles: Getty Conservation Institute.
Pesme, C. (2016) ‘Presentation of Tools Helping to Set a Preservation Target for Displaying Light Sensitive Collection item’, Nuevo Mundo Mundos Nuevos [online], doi: https://doi.org/10.4000/nuevomundo.69241.
Pietsch, K. and Gierstberg, F. (2016) Ulay: what is this thing called Polaroid? Amsterdam: Valiz, pp. 81–115.
Polaroid Corporation (2002) ‘20×24 Worldwide’, pp. 1–7.
Price, B.A., Pretzel, B. and Lomax, S.Q. (2007) Infrared and Raman Users Group Spectral Database, Philadelphia.
Pryme Magazine (2015) ‘The History of Polaroid Chocolate Film’, Pryme Magazine - Annual Journal for Instant Photography . Available at: https://www.tumblr.com/prymemagazine/127239423535/the-history-of-polaroid-chocolate-film. (Accessed: 11 October 2024).
Rebourt E. (1997) La Restauration de trois Polacolor ER (Photographies à dévelopment instantané). Étude de la compatibilité du Polacolor ER avec les solvants organiques. MA dissertation. pp. 20–40. Available at: https://mediatheque-numerique.inp.fr/documentation-oeuvres/memoires-diplome-restaurateurs-patrimoine/restauration-trois-polacolor-er-photographies-developpement-instantane-etude-comptabilite-polacolor-avec-solvants-organiques (Accessed: 20 February 2025).
Reuter J. (2008) ‘Preserving the Polaroid Legacy ’, 20x24 STUDIO. Available at: https://20x24studio.com (Accessed: 3 October 2024).
Reuter, J. (2012) ‘The Fall of Polaroid, The Rebirth of 20×24’, View Camera, May/June, pp. 54–56.
Reuter, J. (2020) ‘20×24 Studio FAQs. Polaroid 20×24 Camera System’, 20×24 Studio. Available at: https://20x24studio.com/?page_id=1653) (Accessed: 20 January 2025).
Reuter, J. (2024) Email to Paulina Miąsik about observations on the stability of Polaroid large-format prints (September 2024-February 2025).
Sutherland, K., Kokkori, M. (2022) ‘Investigating formulations of cellulose acetate plastics in the collections of the Art Institute of Chicago using pyrolysis gas chromatography mass spectrometry’, Journal of Analytical and Applied Pyrolysis 163(2022), pp. 105484.
Stulik, D.C. and Kaplan, A. (2012) ‘Application of a Handheld XRF Spectrometer in Research and Identification of Photographs’, in Shugar, A.N. and Jennifer, L. (eds) Handheld XRF for Art and Archaeology. Vol. 3. Leuven: Leuven University Press, pp. 75–130. DOI: https://doi.org/10.2307/j.ctt9qdzfs.7.
Tsuge, S., Hajime O. and Chuichi W. (2011) Pyrolysis-GC/MS Data Book of Synthetic Polymers Pyrograms, Thermograms and MS of Pyrolyzates. Amsterdam: Elsevier.
Walworth, V.K. and Mervis, S.H. (1989) ‘Instant Photography and Related Reprographic Processes’, in Struge J.M., Walworth V.K. and Shepp, A. (eds) Imaging Processes and Materials; Neblette’s Eighth Edition. New York: Van Nostrand Reinhold, pp. 181–215.
Wilhelm H. (1978) ‘Color Print Instability: A Problem for Collectors and Photographers’, in Norris, D.H., Gutierez, J.J. (2010) Issues in the Conservation of Photographs, Los Angeles: Getty Conservation Institute, pp. 467-468.
Wilhelm, H. and Brower, C. (1993) The Permanence and Care of Color Photographs: Traditional and Digital Color Prints, Color Negatives, Slides, and Motion Pictures. Grinnell, Iowa: Preservation Publishing Company, pp.124–137. Available at: http://wilhelm-research.com/pdf/HW_Book_01_of_20_HiRes_v1c.pdf (Accessed: 20 February 2025).
Wilker, A. (2004) The Composition and Preservation of Instant Film, University of Texas, Austin.
Whitmore, P.M. and Bailie, C. (1999) ‘Predicting the Fading of Objects: Identification of Fugitive Colorants Through Direct Nondestructive Lightfastness Measurements’, Journal of the American Institute for Conservation 38(3), pp. 395–409.
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Copyright (c) 2025 Paulina Mi?sik, Sylvie Pénichon, Clara Granzotto, Ken Sutherland

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